The CANSOLV Integrated SO2–CO2 System enables SO2 and CO2 to be absorbed from the feed gas by counter-current contact with the regenerable amine solvent in the absorption tower. Since the CANSOLV Absorbent DS is extremely selective for SO2; SO2 is absorbed first. The regenerable solvent is fed to the top of the SO2 absorption segment and as it flows down the tower it selectively reacts with SO2 in the feed gas to form an amine-sulfite. The gas goes on to contact the CO2 Absorbent to achieve maximum loading of the CO2 into the regenerable solvent.
At the bottom of the absorption tower, the amine that is rich in SO2 is pumped to a regeneration tower where it is heated to reverse the absorption reaction. As the CANSOLV Absorbent DS moves down the regeneration tower, it is gradually stripped of SO2. The lean amine from the bottom of the regeneration tower is returned to the absorption tower for additional absorption. The same process occurs at the middle for the amine rich in CO2. Sensible heat from both lean amines is used to heat incoming rich amines to maximize heat recovery.
The amount of heat added in the regeneration step will determine the extent to which the CANSOLV absorbent will be stripped of SO2 or CO2 in the regeneration tower. Both the CO2 and SO2 stripped from the CANSOLV absorbents in the regeneration tower are cooled in overhead condensers and are available at positive pressure for utilization.